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Intrinsic Basicities of Phosphorus Imines and Ylides: A Theoretical Study

✍ Scribed by Koppel, Ilmar A.; Schwesinger, Reinhard; Breuer, Thomas; Burk, Peeter; Herodes, Koit; Koppel, Ivar; Leito, Ivo; Mishima, Masaaki

Book ID
119995851
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
132 KB
Volume
105
Category
Article
ISSN
1089-5639

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## Abstract The reaction between dialkyl acetylenedicarboxylates and NH heterocyclic compounds in the presence of trialkyl phosphite leads to stable phosphorus ylide derivatives in good yields. The x‐ray crystallographic data and theoretical study show that there is a resonance between two bonds of