On the Regioselectivity Control in the P
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Giambattista Consiglio; Sylvia C. A. Nefkens; Carmelina Pisano; Fritz Wenzinger
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Article
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1991
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John Wiley and Sons
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German
⚖ 170 KB
## Abstract The regioselectivity of the hydro‐alkoxycarbonylation of methyl acrylate, methacrylate, and crotonate catalyzed by [PdCl~2~L~2~] complexes (L = phosphine ligands) can be largely controlled by variation of the ligands. PPh~3~, promotes preferential carbonylation at the α‐position, wherea