Intramolekulare Aromatenalkylierungen, 30. Mitt.: Synthese von cis-A-8,11a-Dimethyl-7a,8,9,10,11,11a-hexahydro-7H-naphtho [1,8-fg]chinolin und cis-B-6b,10-Dimethyl-6b,7,8,9,10,10a-hexahydro-11H-naphtho[2,1-g]-1-pyrindin
✍ Scribed by Eberhard Reimann; Klaus Pöschl; Hermann Lotter
- Publisher
- John Wiley and Sons
- Year
- 1993
- Tongue
- English
- Weight
- 282 KB
- Volume
- 326
- Category
- Article
- ISSN
- 0365-6233
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Stereochemical Issues Related to the Synthesis of 7,10- 10,16,3':3,4]pyrazino[1,2-b]βcarboline-5,8-diones. -The condensation of iminoethers like (III) with anthranilic acid proceeds with inversion of the tryptophan stereocenter C-16a. Epimerization of the tryptophan center also occurs by acylation
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