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Intramolecularly competitive Ireland Claisen rearrangements: Stereoselective synthesis of alkylidene cyclohexenes

✍ Scribed by Xiaowei Zhang; Matthias C. McIntosh

Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 196 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)01525-1

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✦ Synopsis

Unsymmetrical bis-allyl silylketene acetals derived from cyclohexenones undergo regio-and stereoselective Ireland Claisen rearrangements to afford alkylidene cyclohexenes in good yield.

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