𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Intramolecularly competitive anionic oxy-cope rearrangements

✍ Scribed by Leo A. Paquette; Ronan Guevel; Daryl R. Sauer

Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
231 KB
Volume
33
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Abstrack Two examples of the title maction = described. While the kinetically p&end pathway for 2 utilizes tlw vinyl substituent, that far 16 skirts this option cmnpletely. To a great extent, these biases are a function of the sauctud features inherent to these aicohoir.

Although oxy-cope rearrangements are finding increasing application in the area of nahd products

πŸ“œ SIMILAR VOLUMES

On possible redirection of the course of
On possible redirection of the course of anionic oxy-cope rearrangements
✍ Leo A. Paquette; Donald T. DeRussy; Robin D. Rogers πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 French βš– 921 KB

The p,r-unsaturated ketonea bicyclo[2.2.l]hspt-2-en-7-one (10) and 7,7-dimethoxybicyclo[2.2.l]hept-2-en-S-one (15) have been condensed with lmetalated trans-l-β€’ethoxybutadienea (7a or 7b) and 2-isopropenylcyclopentenea (8b or 8~). Oxyanion formation within the resulting alcohols is followed by skele

A Radical Alternative to the Anionic Oxy
A Radical Alternative to the Anionic Oxy-Cope Rearrangement
✍ Rachel Chuard; Anne Giraud; Philippe Renaud πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 77 KB πŸ‘ 2 views

The anionic oxy-Cope rearrangement has emerged as a highly useful tool for organic synthesis. [1, 2] Various 1,5-dien-3ols readily undergo this electronic reorganization, and the usually easy preparation of the precursors contributes to the popularity of this reaction. However, a limitation of this