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Intramolecular trapping of a cyclopropylidenamine during the favorskii rearrangement of α-chloroketimines

✍ Scribed by Norbert De Kimpe; Elena Stanoeva; Niceas Schamp

Book ID
108381601
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
205 KB
Volume
29
Category
Article
ISSN
0040-4039

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Radical 1.5e.w cyclizations of acylsilanes involving secondary radicals am quite effective. In contrast, 1.6~~ cycliiions are more. sensitive toward steric effect. Tandem radical cycliioa process can be designed. Recently we reported a novel reaction involving addition of primary radicals to the ca