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Intramolecular Redox Processes Induced in Biquinoline-Centered and Metal to Ligand Charge Transfer Excited States of Ru(II)-(4,4‘-bipyridine)-Re(I)- and Ru(II)-(pyrazine)-Re(I)-Containing Dyads

✍ Scribed by Azócar, M. I.; Mikelsons, L.; Ferraudi, G.; Moya, S.; Guerrero, J.; Aguirre, P.; Martinez, C.


Book ID
127152935
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
245 KB
Volume
23
Category
Article
ISSN
0276-7333

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✍ L.K. Orman; J.B. Hopkins 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 352 KB

Picosecond resonance Raman has been employed in a two-color pump/probe experiment to re-evaluate the assignments of metal to ligand charge transfer ground and excited state bands in tris-2,2'-bipyridine Ru(II). It is shown that there is no spectral overlap between ground and excited state bands and