𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Intramolecular rearrangements in phosphoranes via bimolecular intermediates

✍ Scribed by Jeremy I. Musher

Book ID
104246844
Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
174 KB
Volume
14
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Configurational Stability of Oxymethylli
Configurational Stability of Oxymethyllithiums as Intermediates in Intramolecular Rearrangements
✍ Dagmar C. Kapeller; Lothar Brecker; Friedrich Hammerschmidt 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 294 KB

## Abstract Several homochiral oxymethyllithiums, chiral by virtue of the hydrogen isotopes protium and deuterium, were prepared. They were tested for their microscopic configurational stability in intramolecular isomerizations, such as the silyl‐ and germyl‐[1,2]‐__retro__‐Brook and the sigmatropi

Base induced skeletal rearrangements via
Base induced skeletal rearrangements via spirocyclic ipso intermediates in dibenzodithiocinium salts
✍ Katsuo Ohkata; Keiji Okada; Kohji Maruyama; Kin-ya Akiba 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 228 KB

Treatment of 6-methyl-12-oxo-5H,7H-dibenzo[b,g][l,5]dithiocinium salt (&) with methanolic KOH afforded the ring contracted product (a), i. e., thiepin derivatives, trans-z (44%) and cis-2a (19%). However, the corresponding deoxodithiocinium salt (2) gave an unexpected isomer (3) with the same thiepi

Rearrangements in Model Peptide-Type Rad
Rearrangements in Model Peptide-Type Radicals via Intramolecular Hydrogen-Atom Transfer
✍ Damian Moran; Rebecca Jacob; Geoffrey P. F. Wood; Michelle L. Coote; Michael J. 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 German ⚖ 743 KB

## Abstract Intramolecular H‐atom transfer in model peptide‐type radicals was investigated with high‐level quantum‐chemistry calculations. Examination of 1,2‐, 1,3‐, 1,5‐, and 1,6[C ↔ N]‐H shifts, 1,4‐ and 1,7[C ↔ C]‐H shifts, and 1,4[N ↔ N]‐H shifts (__Scheme 1__), was carried out with a number of