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Intramolecular rearrangement in dienetricarbonylruthenium and olefintetracarbonylruthenium type complexes

โœ Scribed by Leonard Kruczynski; Joel L. Martin; Josef Takats


Book ID
108347144
Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
266 KB
Volume
80
Category
Article
ISSN
0022-328X

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## Abstract Intramolecular Hโ€atom transfer in model peptideโ€type radicals was investigated with highโ€level quantumโ€chemistry calculations. Examination of 1,2โ€, 1,3โ€, 1,5โ€, and 1,6[Cโ€…โ†”โ€…N]โ€H shifts, 1,4โ€ and 1,7[Cโ€…โ†”โ€…C]โ€H shifts, and 1,4[Nโ€…โ†”โ€…N]โ€H shifts (__Schemeโ€…1__), was carried out with a number of