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Intramolecular radical additions to the azo group. Fast and indiscriminate 5-exo and 6-endo cyclizations

โœ Scribed by Beckwith, Athelstan L. J.; Wang, Shaofung; Warkentin, John


Book ID
126472777
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
369 KB
Volume
109
Category
Article
ISSN
0002-7863

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Intramolecular addition of alkyllithiums
โœ William F. Bailey; Timo V. Ovaska ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 243 KB

Primary acetylenic alkylliihiums bearing a phenyl substiiueni on the triple bond, which may be prepared in virtually quantitative yield by low-temperature lithium-iodine interchange, undergo regiospecifii 8x0-dig cyclizatiin via stereoselective syn-addition of CHILi to the carbon-carbon triple bond