Intramolecular addition of alkyllithiums
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William F. Bailey; Timo V. Ovaska
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Article
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1990
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Elsevier Science
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French
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Primary acetylenic alkylliihiums bearing a phenyl substiiueni on the triple bond, which may be prepared in virtually quantitative yield by low-temperature lithium-iodine interchange, undergo regiospecifii 8x0-dig cyclizatiin via stereoselective syn-addition of CHILi to the carbon-carbon triple bond