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Intramolecular photocycloaddition of olefin-tethered benzo[a]spiro[2,5]octa-1,4-dien-3-one derivatives

✍ Scribed by Xuqing Zhang; Arthur G. Schultz

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
77 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

Photolysis of benzo[a]spiro [2,5]octa-1,4-dien-3-one derivative 8a afforded spiro-fused tetracycles 10 as a pair of diastereomers in 1.7:1 ratio. The photochemical process occurred by cycloaddition of the intermediate-sulfone stabilized biradical 9 to the tethered olefin. Photolysis of dienone 8b gave only spiro-fused tetracycle 11 without bridged adduct 12.

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