๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Intramolecular Palladium-Catalyzed Aminocarboxylation of Olefins as a Direct Route to Bicyclic Oxazolidinones

โœ Scribed by Elena Borsini; Gianluigi Broggini; Andrea Fasana; Simona Galli; Maisaa Khansaa; Umberto Piarulli; Micol Rigamonti

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
293 KB
Volume
353
Category
Article
ISSN
1615-4150

No coin nor oath required. For personal study only.

โœฆ Synopsis

Abstract

An efficient, direct synthesis of oxazolidinones fused to sixโ€membered heterocyclic rings starting from carbamateโ€protected aminoalkenes has been developed. This procedure is based on an oxidative palladium(II)โ€catalyzed reaction performed in the presence of stoichiometric copper chloride, which is determinant to promote the formation of the bicyclic product and prevent the isolation of the monocyclic amination product. Oxazolidinone compounds arise from a domino aminocarboxylation process through the direct intervention of the carbamate oxygen after the initial palladiumโ€promoted transfer of the nitrogen atom on the C๏ฃพC double bond.

๐Ÿ“œ SIMILAR VOLUMES

ChemInform Abstract: Palladium-Catalyzed
ChemInform Abstract: Palladium-Catalyzed Cyclization/Carbonylation as a Direct Route to 4-[(Methoxycarbonyl)methyl]-3,4-dihydroisoquinolinones (IV), (VI).
โœ G. Attilio Ardizzoia; Egle M. Beccalli; Elena Borsini; Stefano Brenna; Gianluigi ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› John Wiley and Sons โš– 33 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a โ€œFull Textโ€ option. The original article is trackable v

Palladium-Catalyzed Intramolecular N-Ary
Palladium-Catalyzed Intramolecular N-Arylation of Heteroarenes: A Novel and Efficient Route to Benzimidazo[1,2-a]quinolines
โœ C. Venkatesh; G. S. M. Sundaram; H. Ila; H. Junjappa ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons โš– 19 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.