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Intramolecular OH insertion reaction of azido substituted diazoesters and its relevance to the mechanism of the allylic azide rearrangement

✍ Scribed by Albert Padwa; Marcus M. Sá


Book ID
104257489
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
191 KB
Volume
38
Category
Article
ISSN
0040-4039

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ChemInform Abstract: Intramolecular O-H
✍ A. PAWDA; M. M. SA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

Intramolecular O-H Insertion Reaction of Azido Substituted Diazoesters and Its Relevance to the Mechanism of the Allylic Azide Rearrangement. -The Rh(II)-catalyzed decomposition of diazoesters (I), (IV), and (VII) affords the expected O-H insertion products as a mixture of diastereomeric furanones.