ChemInform Abstract: Intramolecular O-H
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A. PAWDA; M. M. SA
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Article
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2010
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John Wiley and Sons
⚖ 33 KB
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Intramolecular O-H Insertion Reaction of Azido Substituted Diazoesters and Its Relevance to the Mechanism of the Allylic Azide Rearrangement. -The Rh(II)-catalyzed decomposition of diazoesters (I), (IV), and (VII) affords the expected O-H insertion products as a mixture of diastereomeric furanones.