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Intramolecular nucleophilic participation. V. The role of the ortho-substituent in the solvolysis of o-nitrobenzhydrl bromide and o-nitrobenzyl tosylate

โœ Scribed by Mease, Alan D.; Strauss, Michael J.; Horman, Ian.; Andrews, L. J.; Keefer, R. M.


Book ID
120910150
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
664 KB
Volume
90
Category
Article
ISSN
0002-7863

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Solvolysis of (o-, m-and p-carboranyl)benzyl toluene-p-sulfonates substituted at the second carbon atom with a phenyl group bearing a range of substituents at the para position has been performed. The rates of hydrolysis of m-and p-carboranyl derivatives measured linearly with increasing electron-re