The reaction rates of 2-chloro-3,5-dinitropyridine 1 with a series of arylthiolates 2a-h in methanol have been measured at 25Β°C. The products are the corresponding 2-thioaryl-3,5-dinitropyridine 3a-h. Good Hammett correlation with value Οͺ1.19 was obtained suggesting an elimination-addition mechanism
β¦ LIBER β¦
Intramolecular nucleophilic cyclization of 3-substituted pyridylalkylamines onto the 2-position of the pyridine ring
β Scribed by Edward M. Hawes; Hubert Lome Davis
- Book ID
- 112122870
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1973
- Tongue
- English
- Weight
- 263 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0022-152X
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