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Intramolecular non-bonded interactions and β- and γ-substituent 13C NMR chemical shifts: application to series of adamantane and norbornane derivatives

✍ Scribed by R. Pachter; P.L. Wessels


Book ID
119116940
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
380 KB
Volume
164
Category
Article
ISSN
0166-1280

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13C NMR spectra of para-substituted methoxybenzenes and phenols were recorded in the solid state to gain an insight into the manner and origin of substantial peak splittings in the ortho (up to 9.2 ppm) and mefa (up to 2.5 ppm) carbon signals. It was difficult to account for these peak splittings on