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Intramolecular Mitsunobu reaction in the regio- and stereoselective synthesis of cis-4,5-disubstituted piperidin-2-ones

✍ Scribed by Nicole Langlois; Olivier Calvez

Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 84 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)01461-1

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✦ Synopsis

Enantiopure cis-4,5-disubstituted piperidin-2-ones were synthesized through the cyclization of O-benzyl hydroxamates under Mitsunobu conditions, followed by samarium diiodide reduction.

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