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Intramolecular isomerization of octahedral complexes by nonbond-rupture mechanisms

โœ Scribed by Brady, James E.


Book ID
126029467
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
248 KB
Volume
8
Category
Article
ISSN
0020-1669

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Mechanism of chiral asymmetry generation
โœ Kouichi Asakura; Dilip K. Kondepudi; Reesheda Martin ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 125 KB ๐Ÿ‘ 1 views

Chiral asymmetry generation, the predominant production of one enantiomer in a non-chiral environment, could occur in the production of the chiral complex cis-[CoBr(NH 3 )(en) 2 ]Br 2 by the reaction of [Co(H 2 O) 2 {(OH) 2 Co(en) 2 } 2 ](SO 4 ) 2 with ammonium bromide in an aqueous medium. The main