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Intramolecular Interconversions in Cyclosilazane Chemistry: A Joint Experimental—Theoretical Study

✍ Scribed by Uwe Klingebiel; Nina Helmold; Stefan Schmatz

Publisher
John Wiley and Sons
Year
2007
Weight
11 KB
Volume
38
Category
Article
ISSN
0931-7597

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✍ Paola Antoniotti; Elena Bottizzo; Lorenza Operti; Roberto Rabezzana; Stefano Bor 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 437 KB 👁 1 views

## Abstract The gas‐phase ion chemistry of GeF~4~ and of its mixtures with water, ammonia and hydrocarbons was investigated by ion trap mass spectrometry (ITMS) and __ab initio__ calculations. Under ITMS conditions, the only fragment detected from ionized GeF~4~ is GeF~3~^+^. This cation is a stron