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Intramolecular “Hydroiminiumation” of Alkenes: Application to the Synthesis of Conjugate Acids of Cyclic Alkyl Amino Carbenes (CAACs).

✍ Scribed by Rodolphe Jazzar; Rian D. Dewhurst; Jean-Baptiste Bourg; Bruno Donnadieu; Yves Canac; Guy Bertrand

Book ID
102001256
Publisher
John Wiley and Sons
Year
2007
Weight
30 KB
Volume
38
Category
Article
ISSN
0931-7597

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## Abstract Deprotonation of __N__‐protected esters of the amino acids alanine 1, ethylglycin 6, valine 7, and phenylalanine 8 with LDA and subsequent addition of various metal salts result in the formation of a probably chelated metal enolate. Aldol reactions of these enolates with aldehydes affor