Intramolecular hydrogen bonds in unsaturated alcohols
โ Scribed by A. E. Lutskii; V. A. Granzhan; Ya. A. Shuster; P. M. Zaitsev
- Publisher
- Springer US
- Year
- 1969
- Tongue
- English
- Weight
- 237 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0021-9037
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Ab tnillo molecular orbltal'theory IS used to study gcomctrtes and encrges of hydrogen-bonded complcxcs between hydrogen fluondc, hydrogen chlondc (as proton donors) and acctylcnc, cthylcnc (as proton acceptors). Symmetrical Tshaped structures arc found lo be equlbnum structures for all four complex
Measurements were made in CCI, of the formation constant K,, of the 1 : l hydrogen-bonded complexes between the reference donor 4-fluorophenol and the intramolecular hydrogen-bonded systems I (one lone pair on heteroatom Y, one intramolecular hydrogen bond: 8-hydroxyquinaldine and 2-(2-hydroxyphenyl