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Intramolecular hydrogen bonding in 2′-substituted anilides

✍ Scribed by B.D. Andrews; I.D. Rae; B.E. Reichert


Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
166 KB
Volume
10
Category
Article
ISSN
0040-4039

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✦ Synopsis


In our recent proton magnetic resonance study of aromatic amines and their derivatives1 we proposed that certain ortho-substituted acetanilides exhibit intramolecular -hydrogen bonding between the amide proton and the ortho-substituent in deuterochlorofo*rm


📜 SIMILAR VOLUMES


1H n.m.r. studies on intramolecular hydr
✍ Bogumil Brzezinski 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 296 KB

## Abstract The ^1^H n.m.r. spectra of eleven anilides of 6‐methyl‐picolinic acid __N__‐oxide in chloroform were obtained. The influence of temperature, concentration and substituents on the chemical shifts of the NH protons was investigated. The structure of the anilides is discussed.

Intramolecular easily polarizable hydrog
✍ B. Brzeziński; G. Zundel 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 470 KB

IR spectra are plotted from anihdes of l-piperidine carbosylic acids CsH reN-(CHa),CONHCeHa-R in CHCla and CDCis solutions. In the cases of n =L and tz =4. weak intramolecular (NH ---N) hydrogen bonds are formed. An asymmetrical energy surface occurs and the proton is present at the N of the anilide