## Abstract The ^1^H n.m.r. spectra of eleven anilides of 6‐methyl‐picolinic acid __N__‐oxide in chloroform were obtained. The influence of temperature, concentration and substituents on the chemical shifts of the NH protons was investigated. The structure of the anilides is discussed.
Intramolecular hydrogen bonding in 2′-substituted anilides
✍ Scribed by B.D. Andrews; I.D. Rae; B.E. Reichert
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 166 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
In our recent proton magnetic resonance study of aromatic amines and their derivatives1 we proposed that certain ortho-substituted acetanilides exhibit intramolecular -hydrogen bonding between the amide proton and the ortho-substituent in deuterochlorofo*rm
📜 SIMILAR VOLUMES
IR spectra are plotted from anihdes of l-piperidine carbosylic acids CsH reN-(CHa),CONHCeHa-R in CHCla and CDCis solutions. In the cases of n =L and tz =4. weak intramolecular (NH ---N) hydrogen bonds are formed. An asymmetrical energy surface occurs and the proton is present at the N of the anilide
Several investigations 2a-f have shown, by a variety of spectral techniques, that 2-fluoro-