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Intramolecular Hydroamination of Unbiased and Functionalized Primary Aminoalkenes Catalyzed by a Rhodium Aminophosphine Complex

✍ Scribed by Julian, Lisa D.; Hartwig, John F.

Book ID
125897299
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
928 KB
Volume
132
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Intramolecular hydroamination/cyclizatio
Intramolecular hydroamination/cyclization of aminoalkenes catalyzed by diamidobinaphthyl magnesium- and zinc-complexes
✍ Patricia Horrillo-MartΓ­nez; Kai C. Hultzsch πŸ“‚ Article πŸ“… 2009 πŸ› Elsevier Science 🌐 French βš– 305 KB

Reaction of 2 equiv of n-Bu 2 Mg and Et 2 Zn with the chiral L-proline-derived axial chiral tetraamines (S,S,S)-1 and (R,S,S)-1 gave the chiral bimetallic complexes [M 2 {(S,S,S)-DABN(MeProline) 2 }{R} 2 ] (M=Mg, R=n-Bu ((S,S,S)-2); M=Zn, R=Et ((S,S,S)-3)) and [M 2 {(R,S,S)-DABN(MeProline) 2 }{R} 2