Intramolecular Hydroamination of Unactived Olefins with Ti(NMe2)4 as a Precatalyst.
โ Scribed by Jason A. Bexrud; J. David Beard; David C. Leitch; Laurel L. Schafer
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 21 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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## Abstract The kinetics and controllability of the Ti[OCH~2~CCl~3~]~4~โinitiated atom transfer radical polymerization (ATRP) of __n__โbutyl acrylate were investigated. Then, with Ti[OCH~2~CCl~3~]~4~ as the initiator, poly(ฯตโcaprolactone)โ__block__โpoly(__n__โbutyl acrylate) (PCLโ__b__โPBA) copolym