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Intramolecular Homolytic Substitution at Selenium: Synthesis of Novel Selenium-Containing Vitamin E Analogues

✍ Scribed by Al-Maharik, Nawaf; Engman, Lars; Malmström, Jonas; Schiesser, Carl H.

Book ID
120083716
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
62 KB
Volume
66
Category
Article
ISSN
0022-3263

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📜 SIMILAR VOLUMES

Rate coefficients for intramolecular hom
Rate coefficients for intramolecular homolytic substitution of oxyacyl radicals at selenium
✍ Heather M. Aitken; Sonia M. Horvat; Carl H. Schiesser; Ching Yeh Lin; Michelle L 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 365 KB

## Abstract Ab initio and density functional calculations predict that intramolecular homolytic substitution reactions of oxyacyl radicals at the selenium atom in ω‐alkylseleno‐substituted radicals proceed via mechanisms that do not involve hypervalent intermediates. When the leaving radical is __t