Intramolecular H Atom Transfer Reactions in Alkyl Radicals and the Ring Strain Energy in the Transition Structure
✍ Scribed by Viskolcz, B.; Lendvay, G.; Körtvélyesi, T.; Seres, L.
- Book ID
- 121272078
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 62 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0002-7863
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An ESR method for studying the mechanism of H-transfer reactions between H-donors of different reactivity (AIH,A,H ...) and their free radicals (Ai,As ...) in non-polar solvents at ambient temperature is presented. The new technique is based on a pulsed initiation of various secondary phenoxy or Ntr
By photolyzing (CF,H),CO and (CFH,),CO the hydrogen atom abstraction reactions of CF,H radicals with (CF,H),CO, H, , D, , CH, , C,H, , n-C,H,, and iso-C,H1,, and the reactions of CFH, radicals with (CFH,),CO and n-C,H,, , have been studied. Arrhenius parameters for these reactions are compared with