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Intramolecular general base catalysis in aprotic solvents

โœ Scribed by Senatore, Lucio; Ciuffarin, Ennio; Isola, Mauro; Vichi, Mario


Book ID
126503877
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
464 KB
Volume
98
Category
Article
ISSN
0002-7863

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The efficiency of intramolecular general
โœ Anthony J. Kirby; Koh Lip Lin ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 114 KB

There is good evidence that intramolecular general base catalysis is much less efficient than intramolecular nucleophilic catalysis.' It has recently been suggested' that this is true only for reactions in aqueous solvents, and that in nonaqueous solvents -and perhaps also in enzyme active sites fro