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Intramolecular fluorescence self-quenching of fluoresceinamine

✍ Scribed by Munkholm, Christiane; Parkinson, Don R.; Walt, David R.

Book ID
111859304
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
653 KB
Volume
112
Category
Article
ISSN
0002-7863

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The fluorescence quenching of a Zn(II) porphyrin linked to Cu(I) catenates relative to a model compound without Cu(I) was attributed to energy transfer from the Zn(II) porphyrin to the metal-to-ligand charge transfer (MLCT) state of the Cu(I) (phenanthroline)~2~ center at the core of the molecules.