The fluorescence of three nearly identical donor-bridge-acceptor molecules was studied under jet-cooled conditions. These compounds contain a I-cyanonaphthalene group as an electron acceptor (A) and an aniline derivative as an electron donor (D). Their only difference is in the substituent on the pa
โฆ LIBER โฆ
Intramolecular exciplex formation in jet-cooled, bichromophoric molecules, II; A dramatic effect of the acceptor electron-affinity
โ Scribed by R. M. Hemant; B. Wegewijs; J. W. Verhoeven; A. G. M. Kunst; R. P. H. Rettschnick
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 192 KB
- Volume
- 107
- Category
- Article
- ISSN
- 0165-0513
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The emissive properties of a bichromophor molecule (1) are reported. This contains an anilino group as an electron donor (D) and a l-cyanonaphthalene group as an electron acceptor (A) interconnected by a saturated hydrocarbon bridge of limited flexibility, which holds D and A far apart in the electr