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Intramolecular Excimer Emission of Triply Bridged [3.3. n ](3,6,9)Carbazolophanes

โœ Scribed by Benten, Hiroaki; Ohkita, Hideo; Ito, Shinzaburo; Yamamoto, Masahide; Sakumoto, Naoki; Hori, Kazushige; Tohda, Yasuo; Tani, Keita; Nakamura, Yosuke; Nishimura, Jun

Book ID
124067309
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
132 KB
Volume
109
Category
Article
ISSN
0022-3654

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Synthesis and photophysical properties o
Synthesis and photophysical properties of syn- and anti-[2.n](3,9)carbazolophanes
โœ Yosuke Nakamura; Masayoshi Kaneko; Noriyuki Yamanaka; Keita Tani; Jun Nishimura ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 348 KB

Both syn-and anri-[2.n](3,9)carbazolophanes (n = 4, 5) were obtained by the intramolecular [2 + 21 photocycloaddition of bis(3-vinyl-N-carbazolyl)alkanes. In the case of R = 4, the syn-isomer afforded sandwich excimer fluorescence, whereas the antiisomer Rave monomer fluorescence.