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Intramolecular Electronic Couplings in Class II/III Organic Mixed-Valence Systems of Bis(1,4-dimethoxybenzene)

✍ Scribed by Yang, Juanhua; Zhang, Weiwei; Si, Yubing; Zhao, Yi


Book ID
126872494
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
978 KB
Volume
116
Category
Article
ISSN
0022-3654

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Electron transfer rate on mixed valence
✍ Toyohiko Nishiumi; Yasuhiro Nomura; Masayoshi Higuchi; Kimihisa Yamamoto πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 English βš– 206 KB

The first example of the determination of the electron transfer rate (k, V , DG Γƒ , k th ) for N ,N 0 -diphenyl-1,4-phenylenediamine derivatives using the Marcus-Hush theory is described. These results were in good agreement with the ones obtained using variable-temperature IR spectra measurements.