Electron transfer rate on mixed valence
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Toyohiko Nishiumi; Yasuhiro Nomura; Masayoshi Higuchi; Kimihisa Yamamoto
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Article
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2003
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Elsevier Science
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English
β 206 KB
The first example of the determination of the electron transfer rate (k, V , DG Γ , k th ) for N ,N 0 -diphenyl-1,4-phenylenediamine derivatives using the Marcus-Hush theory is described. These results were in good agreement with the ones obtained using variable-temperature IR spectra measurements.