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Intramolecular electron transfer from pentacyanoferrate(II) to pentaamminecobalt(III): linkage isomers of 3- and 4-cyanopyridine as bridging ligands

โœ Scribed by Szecsy, Alek P.; Haim, Albert


Book ID
120537738
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
928 KB
Volume
104
Category
Article
ISSN
0002-7863

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Intramolecular Electron Transfer from Ir
โœ Dipl.-Chem. Horst Bertram; Prof. Dr. Karl Wieghardt ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 195 KB

Compound ( 1 ) (0.68g, 4mmol) is dissolved under N2 in anhydrous tetrahydrofuran (50 ml). To this solution, cooled to -113"C, is added dropwise a solution of tert-butyllithium in n-pentane (3ml,5.1 mmol; ca. 1.7 M solution). After 15min the olefin or carbonyl compound (8mmol) is addedC6]. The soluti