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Intramolecular electron-transfer excited state in 6-cyanobenzquinuclidine

✍ Scribed by Krystyna Rotkiewicz; Wiesz.xl;lawa Rubaszewska

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
398 KB
Volume
70
Category
Article
ISSN
0009-2614

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✦ Synopsis

Recervcd 23 November 1979; m final form 10 December 1979 6-cyanobenzquinuchdmc has a ngd structure wrth the lone-pau orbrtal of the ammo-group mtrogen atom and the norbrtals of the aromntrc rmg mutually perpcndrcular. It 1s a model for the previously postulated twrsted rnternal chargetrnnsfcr cxcrted states. The fluorcsccnt smglet state was rdentrfied as a strongly polar state with a full charge separation, observed m absorption as the t(n, rr*) ewttcd state. The results strongly support the twtsted Internal charge-transfer state hypothesrs.

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