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Intramolecular Dynamics of Tetranuclear Iridium Carbonyl Cluster Compounds. Part V. Polysubstituted derivatives of [Ir4(CO)12]

✍ Scribed by Andrés Strawczynski; Chris Hall; Giacomo Bondietti; Renzo Ros; Raymond Roulet


Publisher
John Wiley and Sons
Year
1994
Tongue
German
Weight
814 KB
Volume
77
Category
Article
ISSN
0018-019X

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📜 SIMILAR VOLUMES


Intramolecular Dynamics of Tetranuclear
✍ Andrès Strawczynski; Gianfranco Suardi; Renzo Ros; Raymond Roulet 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 German ⚖ 802 KB

## Decacarbonyl/~,-bis(methylthio)methane]tetrairidium ([Ir4(C0) ,,(p2-CH3SCH2SCH3)], 14). A soln. of 2 (272 mg, 0.204 mmol) and bis(methy1thio)methane (259 pl, 2.54 mmol) in CH2C1, (130 ml) was stirred with AgBF, (51 mg, 0.26 mmol) for 1 h at 258 K under Ar, then passed through a column of silic

Intramolecular Dynamics of Tetranuclear
✍ Gianfranco Suardi; Andres Strawczynski; Renzo Ros; Raymond Roulet; Fabrizia Grep 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 German ⚖ 376 KB

## Abstract The title complex crystallises in two __C__~__3v__~, isomeric forms differing in carbonyl‐ligand arrangement. In solution, the isomer 1b with three edge‐bridging carbonyls on a common face of the metal tetrahedron converts __via__ an endothermic equilibrium into the isomer 1u with no br