Intramolecular Dynamics of Tetranuclear Iridium Carbonyl Cluster Compounds. Part V. Polysubstituted derivatives of [Ir4(CO)12]
✍ Scribed by Andrés Strawczynski; Chris Hall; Giacomo Bondietti; Renzo Ros; Raymond Roulet
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- German
- Weight
- 814 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0018-019X
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## Decacarbonyl/~,-bis(methylthio)methane]tetrairidium ([Ir4(C0) ,,(p2-CH3SCH2SCH3)], 14). A soln. of 2 (272 mg, 0.204 mmol) and bis(methy1thio)methane (259 pl, 2.54 mmol) in CH2C1, (130 ml) was stirred with AgBF, (51 mg, 0.26 mmol) for 1 h at 258 K under Ar, then passed through a column of silic
## Abstract The title complex crystallises in two __C__~__3v__~, isomeric forms differing in carbonyl‐ligand arrangement. In solution, the isomer 1b with three edge‐bridging carbonyls on a common face of the metal tetrahedron converts __via__ an endothermic equilibrium into the isomer 1u with no br