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Intramolecular Diels−Alder Reaction by Self-Assembly of the Components on a Lewis Acid Template

✍ Scribed by Ward, Dale E.; Abaee, Mohammad Saeed


Book ID
111918044
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
144 KB
Volume
2
Category
Article
ISSN
1523-7060

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On the mechanism of Diels—Alder reaction
✍ V. Branchadell; A. Oliva; J. Bertran 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 261 KB

The effect of Lewis acid catalysts on the mechanism of Diels-Alder reactions is studied using the MINDO/3 method. It is found that they tend to increase the two-step character of the process through a more important participation of the charge-transfer configuration.