Intramolecular Diels-Alder reactions. VI. Synthesis of 3-hydroxymethyl-2-naphthoic acid lactones
β Scribed by Klemm, LeRoy H.; Klemm, R. A.; Santhanam, P. S.; White, Danny Vincent
- Book ID
- 125508672
- Publisher
- American Chemical Society
- Year
- 1971
- Tongue
- English
- Weight
- 636 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0022-3263
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Dichloropyrazinones are reacted with alkenolates or a Grignard reagent in order to tether a dienophilic side-chain at the 3-position. The compounds smoothly undergo intramolecular Diels-Alder reaction forming tricyclic ring systems. The reactions proceed completely stereoselective yielding only endo