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Intramolecular Diels-Alder reactions. V. Synthesis of dehydro-.beta.-peltatin methyl ether

✍ Scribed by Klemm, LeRoy H.; Santhanam, Peruvemba


Book ID
125898243
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
314 KB
Volume
33
Category
Article
ISSN
0022-3263

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## Abstract The tandem Knoevenagel hetero Diels‐Alder reaction of 4,4,4‐trichloro‐3‐oxobutanal (4), the malondialdehyde derivative 11a, and the enol ether 13 was followed by separation of the diastereomers and treatment with DBU in methanol. Thermolysis in xylene then gave the secologanin derivativ