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Intramolecular Diels-Alder reactions of unsaturated acylcyclopentadienes and cyclopentadienecarboxylates

✍ Scribed by Hewawasam Piyasena; Y.N. Gupta; Debabrata Mukherjee; K.N. Houk


Book ID
104216333
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
212 KB
Volume
29
Category
Article
ISSN
0040-4039

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✦ Synopsis


The drmers of unsaturated acylcyclopentadrenes and cyclopentadrenecarboxylates have been synthesrzed Pyrolyses provide monomers which undergo the mtramolecular cycloaddtnons Three types of adducts are obtamed Intramolecular Duels-Alder cycloaddrnons are very useful m synthesis 2*3 Although the prmcrple IS wellestablished, new types and appbcatrons are reported frequently


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