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Intramolecular Diels-Alder reactions of sulfur-substituted dienes via 3-sulfolenes

✍ Scribed by Chou, Shang Shing P.; Wey, Shiow Jyi

Book ID
127221680
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
669 KB
Volume
55
Category
Article
ISSN
0022-3263

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The geometryof dienesobtainedfrom2,3-substitutedsulfolenesbearinga 3-carboxyl derivativeis dependenton the natureof the 3-carboxygroupand on the functionalityof the 2substituent. These factorsthereforehavea crucialinfluenceon the stereoselectivityof subsequentDiels-Alderreactions, @ 1997Publishedby