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Intramolecular Cyclopropanation of Glycals: Studies toward the Synthesis of Canadensolide, Sporothriolide, and Xylobovide

✍ Scribed by Yu, Ming; Lynch, Vincent; Pagenkopf, Brian L.


Book ID
118137257
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
65 KB
Volume
3
Category
Article
ISSN
1523-7060

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✍ Michael T. Crimmins; James B. Thomas πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 243 KB

The synthesis of a pentacyclic model 14 for ginkgolides A and B has been accomplished utilizing an intramolecular furan-enone photochemical cycloaddition as the key transformation. Ginkgolides A and B 1,2, hexacyclic trilactones obtained from extracts of the ancient tree Ginkgo Biloba, were isolated