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Intramolecular cycloaddition of 3-O-cyclohexenyl carbohydrate nitrones: Diastereoselective synthesis of optically pure tetrahydropyrano[2,3]cyclohexane derivatives

✍ Scribed by Ashoke Bhattacharjee; Anup Bhattacharjya; Amarendra Patra


Book ID
103405681
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
89 KB
Volume
37
Category
Article
ISSN
0040-4039

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Optically Pure 3,6-Dioxazocan-2-one Deri
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Azidoformates derived from chiral enol ethers, when hydrolysis of 7 gives a single derivative of 2-aminocyclohexanone. irradiated, give 3,6-dioxazocan-2-one derivatives 7 by a highly diastereoselective intramolecular cycloaddition. The [a] Dipartimento di Chimica dellЈUniversita `di Roma "La Sapienz