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Intramolecular cyclizations of organometallic compounds. I. The thermal rearrangement of 4-lithio-1,7-octadiene

✍ Scribed by Stanley E. Wilson

Publisher: Elsevier Science
Year: 1975
Tongue: French
Weight: 191 KB
Volume: 16
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)91043-8

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✦ Synopsis

Any reaction that results in ring formation can be of considerable potential use in organic synthesis. It has been recognized for several years that a carbon-carbon double bond can experience insertion into a carbon-lithium bond resulting in the formation of a new carbor carbon u linkage.' If the double bond were incorporated in the lithium reagent (,J+), such an intramolecular reaction would result in ring formation.' In those systems which have been

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