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Intramolecular cyclization of arylnitrenium ions. Formation of carbon-carbon bonds and of lactones

✍ Scribed by Abramovitch, Rudolph A.; Cooper, Melanie; Iyer, Suresh; Jeyaraman, Ramasubbu; Rodrigues, J. Augusto Rosario

Book ID
121187937
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
260 KB
Volume
47
Category
Article
ISSN
0022-3263

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✍ Rudolph A. Abramovitch; Joseph Miller; Antonio J.C. de Souza πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 206 KB

The synthesis of an aminodibenzo [a,c]octadiene and an aminodibenzo[a,c]octatriene, guided by molecular mechanics calculations, was effected by the intramolecular cyclization of the corresponding open chain nitrenium ions. Also reported is the predicted failure to synthesize another aminodibenzo[a,c