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Intramolecular cyclization of alkenyl radicals generated by 1,5-hydrogen transfer to alkoxy radicals

✍ Scribed by Ẑivorad Čeković; Dimitar Ilijev

Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
218 KB
Volume
29
Category
Article
ISSN
0040-4039

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A free radical introduction of a functionalized alkyl chain onto remote non-activated 8-carbon atoms (Michael type alkylation) has been achieved Photolysis of suitable alkyl nitrites involves generation of 8-alkyl radicals and in the presence of radicophilic olefins, intermolecular addition takes pl