Intramolecular cyclization of 2-alkynyl benzyl azides in the presence of AuCl 3 and AgSbF 6 in THF under a pressured vial at 100 Β°C gives the corresponding isoquinolines in good yields. Similarly, the five-membered analogs afford the corresponding isoquinolines.
Intramolecular cyclization of 2-biarylsulfonyl azides
β Scribed by Abramovitch, Rudolph A.; Chellathurai, Therinadar; McMaster, Ian T.; Takaya, Takao; Azogu, Christopher I.; Vanderpool, Danny P.
- Book ID
- 127230637
- Publisher
- American Chemical Society
- Year
- 1977
- Tongue
- English
- Weight
- 920 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0022-3263
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