Intramolecular charge transfer properties of dicyanovinyl-substituted aromatics
β Scribed by Katritzky, Alan R.; Zhu, Dong Wei; Schanze, Kirk S.
- Book ID
- 120191236
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 750 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0022-3654
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π SIMILAR VOLUMES
The charge transfer mechanism of aromatic substitution presented by the present author and Tanaka in the previous paper is further developed from the viewpoint of the resonance interaction between no-bond and charge-transfer structures. According to the present mechanism which includes symmetrical c
LIF excitation spectra have been recorded for a family of molecules whose dual fluorescence in solution has been ascribed to twisted intramolecular charge transfer (TICT) state formation, promoted through torsional motion in the initially photoexcited state. To eliminate the influence of solvation,