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Intramolecular charge transfer inπ-conjugated oligomers: a theoretical study on the effect of temperature and oxidation state

✍ Scribed by Massimiliano Aschi; Maira D’Alessandro; Monica Pellegrino; Alfredo Di Nola; Marco D’Abramo; Andrea Amadei


Publisher
Springer
Year
2008
Tongue
English
Weight
431 KB
Volume
119
Category
Article
ISSN
1432-2234

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Intramolecular 2pπ* → 3dπ charge transfe
✍ Haruo Shizuka; Katsuhiko Okazaki; Masayuki Tanaka; Mitsuo Ishikawa; Minoru Sumit 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 366 KB

In~mol~~ 2pn\* + 3dn charge transfer in the excited state of phenyl~e occurs very rapidly (<IO ps) both in ?&Fat 293 K and in EPA glass at 77 K. At room temperature a Iong;lived 425 nm transient (which is assgned to a reananged intermediate) is produced with a nse time of 30 ps, showing that the tra