Intramolecular charge transfer inπ-conjugated oligomers: a theoretical study on the effect of temperature and oxidation state
✍ Scribed by Massimiliano Aschi; Maira D’Alessandro; Monica Pellegrino; Alfredo Di Nola; Marco D’Abramo; Andrea Amadei
- Publisher
- Springer
- Year
- 2008
- Tongue
- English
- Weight
- 431 KB
- Volume
- 119
- Category
- Article
- ISSN
- 1432-2234
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In~mol~~ 2pn\* + 3dn charge transfer in the excited state of phenyl~e occurs very rapidly (<IO ps) both in ?&Fat 293 K and in EPA glass at 77 K. At room temperature a Iong;lived 425 nm transient (which is assgned to a reananged intermediate) is produced with a nse time of 30 ps, showing that the tra
We treat the electric field effect on electron transfer processes. As an application, the effect of electric field on the Marcus-Levich theory is presented. For comparison, the electric field effect on absorption spectra is also discussed.