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Intramolecular charge transfer in 5-phenyl-3H-1,2-dithiole-3-thione and 5-phenyl-3H-1,2-dithiole-3-one derivative molecules for quadratic nonlinear optics

✍ Scribed by Alain Botrel; Bertrand Illien; Péter Rajczy; Isabelle Ledoux; Joseph Zyss


Publisher
Springer
Year
1993
Tongue
English
Weight
995 KB
Volume
87
Category
Article
ISSN
1432-2234

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One-pot synthesis, structure, theoretica
✍ Yanning Cao; Hanhui Zhang; Yiji Lin; Changcang Huang; Yiping Chen; Fengli Zhang; 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 648 KB

A novel D3T derivative, 5-amino-4-cyano-3H-1,2-dithiole-3-thione (compound 1) has been obtained in one-pot reaction. The crystal is orthorhombic, space group Pbca, with a = 10.3667(4) A ˚, b = 10.8898(4) A ˚, c = 11.4942(5) A ˚, V = 1297.60(9) A ˚3, and Z = 8. In the crystal, molecules are firstly s