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Intramolecular Charge Transfer in 4-Aminobenzonitriles Does Not Necessarily Need the Twist

✍ Scribed by Gómez, Isabel; Reguero, Mar; Boggio-Pasqua, Martial; Robb, Michael A.


Book ID
118031585
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
547 KB
Volume
127
Category
Article
ISSN
0002-7863

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✍ O. Kajimoto; T. Nayuki; T. Kobayashi 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 325 KB

The rate of formation of the intramolecular charge-transfer state of 4-(N,N-dimethylamino)benzonitrile (DMABN) has been determined in supercritical CFsH using a fast single-photon counting technique. The rate constant increases rapidly with increasing CFIH density, indicating the importance of the p