✦ LIBER ✦
Intramolecular charge-transfer fluorescence of 1-phenyl-4-[(4-cyano-1-naphthyl)methylene]piperidine (fluoroprobe) as a sensor for phase transitions in the solid state
✍ Scribed by Leonardus W. Jenneskens; Herman J. Verhey; Hendrik J. van Ramesdonk; Jan W. Verhoeven; Kees F. van Malssen; Henk Schenk
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 434 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0165-0513
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✦ Synopsis
Abstract
As evidenced by temperature‐dependent wide‐angle X‐ray diffraction (WAXD), the thermochromism of the continuous and time‐resolved (nanosecond time scale) fluorescence behaviour of 1‐phenyl‐4‐[(4‐cyano‐1‐naphthyl)methylene]piperidine (fluoroprobe) dissolved in octadecyl octadecanoate is shown to be a highly sensitive probe for a phase transition in the solid state occurring in the latter.